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Extra info for Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity. Symposia Papers Presented at the Fourth International Congress of Pesticide Chemistry, Zurich, Switzerland, July 24–28, 1978

Sample text

Finally as the role of transition metals in biological systems is increasingly understood new bio-organometallic reagents will be developed which will further advance the capability of the synthetic chemist. Organophosphorus chemistry has had a tremendous impact in the area of insecticides where a gigantic volume of literature exists on the subject. As some of the papers will illustrate,there is still new ground to be covered in this area. More recently phosphonate chemistry has provided one of the most exciting herbicides the pesticide industry has yet seen.

N. HARRIS, J. L. HUPP ATZ, J. N. PHILLIPS AND T. TEITEI CSIRO, Division of Plant Industry, Canberra, Australia. Abstract - Compounds related to the auxin transport inhibitor l-(2,carboxyphenyl)3-phenylpropan-l,3-dione, in which the 3-diketone moiety has been replaced by five and six membered heterocyclic systems, are discussed. The syntheses of four pyrimidine analogues are described, three of which involve Vilsmeier type amideacid chloride intermediates in the formation of the heterocyclic ring.

R. Wegler and L. E u e ,i n Chemie der Pflanzenschutz- und Schädlinqsbekämpfunqsmi t t e l , V o l . 5, Ed. R. W e g l e r , S p r i n g e r - V e r l a g, Berlin 1 9 7 7 , p. 7. H. Nelson et al 25(1 ) , 1 2 0 , ( 1 9 4 9 ) . Soap (a) J apan Pats, 453" 4 6 2 . 1 0 8 ; (b) U S . 398 ( 1 9 6 6 ) . US. P a t . 903 0 9 0 ( 1 9 7 5 ; cTTael , J . [2] 4 6 , 298 ( 1 8 9 2 ) . τ t , Ber. deutsch ehem. G e s . 6J_, 2131 ( 1 9 2 8 ) . T a r b e l l and P. D Bartlett, J. Amer. chem. Soc. 59, 407 (1937), Harkes (to U n i l e v e r ) , U S .

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